成果管理

近日，材料及能源化学领域的顶尖期刊、英国皇家化学学会旗下的Journal of Materials Chemistry A（SCI一区TOP期刊，影响因子11.301）以研究论文的形式发表了我院孙强强老师课题组——分析检测研究团队的最新研究成果。

论文题目为“Pulsed electrodeposition of well-ordered nanoporous Cu-doped Ni arrays promotes highefficiency overall hydrazine splitting”（J. Mater. Chem. A,2020, 8, 21084-21093, DOI:10.1039/d0ta08078k），我院教师孙强强为论文第一作者，我校为论文的第一完成单位。

碱性电解水制氢是大规模工业化制氢的重要途径。然而，电解过程中阴阳两极较大的过电位大大限制了其规模化应用。开发低成本且具有高能量密度、高催化活性的电极材料具有重要的意义。镍铜合金基电极材料因其廉价的成本、丰富的储量以及强烈的金属协同催化作用，在能源转化领域具有广阔的应用前景。

孙强强课题组基于脉冲电沉积法及原位恒电位溶出法，设计了一种具有三维纳米方孔阵列结构的铜合金电极材料（Ni(Cu) CNPs）（图2）。在电解水析氢（Hydrogen evolution reaction, HER）及肼氧化（Hydrazine Oxidation Reaction, HzOR）性能测试中，Ni(Cu) CNPs表现出优异催化性能及稳定性。在10 mA cm-2的电流密度时，析氢过电势仅为41 mV，而肼氧化工作电位仅为-18 mV。应用于实际双功能电解槽，大大降低了电解水的电能消耗，更显著优于市场商用贵金属催化剂（Pt/C），为其在电解水产氢的规模化应用奠定了基础。此外，对阳极催化过程催化机理的研究发现，水合肼在Ni(Cu) CNPs表面中发生两步反应，先氧化失去2电子形成二氮烯，再氧化失去2电子形成气体产物N2，对镍铜合金在直接肼燃料电池（Direct Hydrazine Fuel Cell, DHFC）领域的应用发展具有重要的现实意义。

孙强强老师自2018年以来，以第一作者发表SCI论文6篇，申请发明专利3项，其中一区论文2篇，二区论文2篇，四区2篇，影响因子总和超过36。该项成果是分析检测团队2020年以来的第6篇SCI论文，课题组三年来发表SCI论文15篇，影响因子总和达57。主要论文包括：

[1] Qiangqiang Sun, Yibing Li, Jianfang Wang, Baoyue Cao, Yan Yu, Chunsheng Zhou, Guochun Zhang, Zenglin Wang, Chuan Zhao. Pulsed electrodeposition of well-ordered nanoporous Cu-doped Ni arrays promotes high efficiency overall hydrazine splitting, J. Mater. Chem. A,2020, 8, 21084-21093. (IF=11.30, 一区)

[2]Qiangqiang Sun, Yujuan Dong, Zenglin Wang, Shiwei Yin, Chuan Zhao, Synergistic nanotubular copper-doped nickel catalysts for hydrogen evolution reactions, Small, 2018, 14, 1704137. (IF= 9.598, 一区)

[3] Qiangqiang Sun, Liyuan Wang, Yuqian Shen, Meng Zhou, Yi Ma, Zenglin Wang, Chuan Zhao, Bifunctional Copper-Doped Nickel Catalysts Enable Energy-Efficient Hydrogen Production via Hydrazine Oxidation and Hydrogen Evolution Reaction. ACS Sustainable Chemistry & Engineering, 2018. 6, 12746-12754. (IF = 6.140, 二区)

[4] Qiangqiang Sun, Meng Zhou, Liyuan Wang, Yuqian Shen, Meng Zhou, Yi Ma, Yibing Li, Xin Bo, Zenglin Wang, Chuan Zhao, Hierarchical Nanoporous Ni(Cu) Alloy Anchored on Amorphous NiFeP as Efficient Bifunctional Electrocatalysts for Hydrogen Evolution and Hydrazine Oxidation. Journal of Catalysis, 2019, 373, 180-189. (IF =6.759, 二区)

[5] Jianfang Wang, Heping Yang, Chunsheng Zhou, Jie Xu, Jun Wang, Youliang Ren, Template-assisted preparation of MnO2@MnO2 hollow nanospheres and their research of capacitance performance. Materials Letters, 2020,262,127139. (IF =3.204, 三区)

[6] Jianfang Wang, Heping Yang, Liping Kang, Zonghuai Liu, Gaini Zhang, Lijun Ren, Jie Xu. Salt-template assisted preparation and electrochemical performance of MnO/C nanosheet composite electrode for lithium-ion battery. Journal of Solid State Chemistry, 2018, 264:134-140. (IF =2.726, 三区)

[7] Xuemei Fan, Shumin Wang, Zhejian Li, Yimeng Wang, Xinhui Fan, Lingmin Yu.

An electrochemiluminescence biosensor for the determination of mercury ion via dual- amplification strategy. J Brazil Chem Soc. 2020.(IF=1.399，化学四区)

[8] Xuemei Fan, Zhejian Li, Shumin Wang, Yimeng Wang, Lingmin Yu, Xinhui Fan. An electrochemiluminescent sandwich biosensor for the detection of lipopolysaccharide. Quim. Nova, 2020,43(6):747-751.(IF= 0.668，化学四区)